Published
2022-11-21
Section
Review Article
How to Cite
Dialkyl Carbonate Synthesis: Recent Scientific And Technological Advancements
Bhavya Dhami
Department of Chemical Engineering, Institute of Chemical Technology, Matunga, Mumbai, 400019.
DOI: https://doi.org/10.36664/bt/2022/v69i1/172485
Keywords: dialkyl carbonates, green solvent, catalysis, modern methods of synthesis.
Abstract
Dialkyl Carbonates (DAC's) are essential organic compounds (structurally seen as esters of carbonic acid) that have gained significant importance over the last few decades. They can be used as solvents, reagents, and for the synthesis of various organic compounds such as 5-6 membered heterocyclic compounds, indolines, and piperidines. They are highly versatile since they are used in the pharmaceutical, cosmetic, petrochemical, and agricultural industries. They are also used as solvents in Li-ion batteries, pesticides, fertilizers, polymer synthesis, beauty products, paints and coatings. This article analyses the different synthetic methods of DAC's, technological advancements in their syntheses, and the innovation with respect to discoveries of catalysts for these syntheses. It also includes its applications in various industries and uses in other reactions.
Downloads
References
Pietro Tundo, Manuele Musolino, Fabio Aricò, Front Chem., 2019, 7, 300
Khuong Q. Vuong, Reinhard Effenberger, Joseph Zilberman, Simon Smart, Craig M. Williams, and Eric W. McFarland, ACS Sustain. Chem. Eng., 2017, 5:7, 38
Shouying Huang, Bing Yan, Shengping Wang and Xinbin Ma, Chem. Soc. Rev., 2015, 44, 3079
Praveen Kumar, Vimal Chandra Srivastava, Urška Lavrenčič Štangar, Branka Mušič, Indra Mani Mishra & Yuezhong Meng, Catal. Rev. - Sci. Eng., 2019, 63:3, 363
Shaikh, Abbas-Alli G.; Swaminathan Sivaram, Organic carbonates, Chem. Rev., 1996, 96, 951
Dajian Zhu, Fuming Mei, Lijuan Chen, Tao Li, Wanling Mo, Guangxing Li, Energy Fuels, 2009, 23, 2359
Tokuo Matsuzaki and Asumaru Nakamura, Catal. Surv. Jpn., 1997, 1, 77
Yingshuai Jia, Guofeng Zhao, Ye Liu, Yong Lu, Catal. Commun., 2019, 126, 1
Tobias Keller, Johannes Holtbruegge, Alexander Niesbach, Andrzej Gorak, Ind. Eng. Chem. Res.,2011, 50, 11073
M. Malyaadri, K. Jagadeeswaraiah, P.S. Sai Prasad, N. Lingaiah, Appl. Catal. A: Ge., 2011, 401, 153
Shekhar M Dhuri and Vijaykumar V Mahajani, J. Chem. Technol. Biotechnol., 2006, 81, 62
Zhen-Zhen Yang, Liang-Nian He *, Xiao-Yong Dou, Sébastien Chanfreau, Tetrahedron Lett., 2010, 51, 2931
Georgiana Stoica, Snia Abell, Javier Prez-Ramrez, ChemSusChem, 2009, 2, 301
Mei Fuming, Li Guangxing, Nie Jin, Xu Huibi, J Mol Catal A Chem, 2002, 184, 465
Guoming Zhao, Jinghui Shi, Gang Liu, Yan Liu, Zhenlu Wanga, Wenxiang Zhanga, Mingjun Jiaa, J Mol Catal A Chem, 2010, 327, 32
A. Angelini, A. Dibenedetto, D. Curulla-Ferré, M. Aresta, RSCAdv., 2015, 45, 134
Mouhua Wang, Ning Zhao, Wei Wei, Yuhan Sun, Ind. Eng. Chem. Res., 2005, 44, 7596
Yu Feng, Junling Yang, Fulong Zhao, Asian J. Chem., 2014, 26:4, 1232
Wenbo Zhao, Weicai Peng, Dengfeng Wang, Ning Zhao, Junping Li, Fukui Xiao, Wei Wei, Yuhan Sun, Catal. Commun., 2009, 10, 655
Nicole Kindermann, Tharun Jose, Arjan W. Kleij, Top. Curr. Chem. (Z), 2017, 375:15, 15
Atul Bansode, Atsushi Urakawa, ACS Catal., 2014, 4:11, 3877
Hajime Ohno, Mahdi Ikhlayel, Masazumi Tamura, Kenji Nakao, Kimihito Suzuki, Kentaro Morita, Yuzuru Kato, Keiichi Tomishige, Yasuhiro Fukushima, Green Chem., 2020, 23, 457
R.Dedryve`re, L. Gireaud, S. Grugeon, S. Laruelle, J.M. Tarascon, D. Gonbeau, J. Phys. Chem. B, 2005, 109, 15868
Ayoub O.G. Abdalla, Dong Liu, Energies, 2018, 11, 1552
Mingzhang Pan, Weiwei Qian, Zeyuan Zhang, Rong Huang, Xiaorong Zhou, Haozhong Huang, Mingxing Li, Fuel, 2019, 257, 115920
P. Tundo and M. Selva, Acc. Res . Chem., 2002, 35, 706
H. Babad and A. G. Zeiler, Chem .Rev,. 1973, 73, 75
Y. Y. Gao, W. C. Peng, N. Zhao, W. Wei and Y. H. Sun, J. Mol. Catal. A: Chem., 2011, 359, 29
Tomishige K, Furusawa Y, Ikeda Y, Asadullah M, Fujimoto K., Catal. Lett., 2001, 76, 71
Honda M, Kuno S, Begum N, Fujimoto K, Suzuki K, Nakagawa Y, Tomishige K, Appl. Catal. A., 2010, 384, 165
